Tech
Where does your glass come from?
The word “local” has become synonymous with sustainability, whether it’s food, clothes or the materials used to construct buildings. But while consumers can probably go to a local lumberyard to buy lumber from sustainably grown trees cut at nearby sawmills, no one asks for local glass.
If they did, it would be hard to give an answer.
The raw materials that go into glass—silica sand, soda ash and limestone—are natural, but the sources of those materials are rarely known to the buyer.
The process by which sand becomes sheets of glass is often far from transparent. The sand, which makes up over 70% of glass, could come from a faraway riverbed, lakeshore or inland limestone outcrop. Sand with at least 95% silica content is called silica sand, and only the purest is suitable for architectural glass production. Such sand is found in limited areas.
If the glass is colorless, its potential sources are even more limited, because colorless low-iron glass—popularized by Apple’s flagship stores and luxury towers around the world—requires 99% pure silica sand.
Glass production in Venice
The mysteries of glass production have a historical precedent that can be traced back to trade secrets of the Venetian Empire.
Venice, particularly the island of Murano, became the center for glass production largely due to its strategic location for importing raw materials and production know-how and exporting coveted glass objects.
From the 11th to the 16th centuries, the secrets of glassmaking were protected by the Venetians until three glassmakers were smuggled out by King Louis XIV of France, who applied the technology to create the Palace of Versailles’ Hall of Mirrors.
Venice was an otherwise unlikely location for glassmaking.
Neither the primary materials of sand and soda ash (sodium carbonate) nor the firewood of the medieval Venetian glassmakers were found in the city’s immediate vicinity. They were transported from the riverbeds of the Ticino River in Switzerland and the Agide River, which flows from the Austria-Switzerland border to the Adriatic Sea south of Venice. Soda ash, which is needed to lower the melting point of silica sand, was brought from Syria and Egypt.
So Venetian glass production was not local; it was dependent on precious resources imported from afar on ships.
Rising demand for low-iron, seamless glass
In the past few decades, low-iron glass, known for its colorlessness, has become the contemporary symbol of high-end architecture. The glass appears to disappear.
Low-iron glass is made from ultrapure sand that is low in iron oxide. Iron causes the green tint seen in ordinary glass. In architecture, low-iron glass doesn’t affect the performance—only the appearance. But it is prized.
In the U.S., this type of sand is found in a few locations, primarily in Minnesota, Wisconsin, Illinois and Missouri, where sand as white and fine as sugar—thus called saccharoidal—is mined from St. Peter sandstone. Other locations where it can be found around the world include Queensland in Australia and parts of China. Less pure sand can be purified by methods such as acid washing or magnetic separation.
Perhaps no corporation has popularized low-iron and seamless glass in architecture more than the technology giant Apple.
Glass has become fundamentally linked with Apple’s products and architecture, including its flagship stores’ expensive and daring experiments in architectural uses of glass.
Apple’s first showroom, completed in Soho in New York in 2002, showcased all-glass stairs that were strengthened with hurricane- and bullet-resistant plastic interlayers sandwiched between five sheets of glass. The treads attach to all glass walls with hockey puck-sized titanium hardware, making both the glass stairs and the shoppers appear to float.
The company’s iconic flagship store near New York’s Central Park is an all-glass cube measuring 32.5 feet (10 meters) on each side and serving as a vestibule to the store below. The first version was completed in 2006 using 90 panels, which was a technical feat. Then, in 2011, Apple reconstructed the cube in the same location, same size, but with only 15 panels, minimizing the number of seams and hardware while maximizing transparency.
Today, low-iron glass has become the standard for high-profile architecture and those who can afford it, including the “pencil towers” in Manhattan’s Billionaires’ Row.
Glass’s climate impact
Glass walls common in high-rise buildings today have other drawbacks. They help to heat up the room during increasingly hot summers and contribute to heat loss in winter, increasing dependence on artificial cooling and heating.
The glassmaking process is energy intensive and relies on nonrenewable resources.
To bring sand to its molten state, the furnace must be heated to over 2,700 degrees Fahrenheit (1,500 degrees Celsius) for as long as 50 hours, which requires burning fossil fuels such as natural gas, releasing greenhouse gases. Once heated to that temperature, the furnace runs 24/7 and is rarely shut down.
The soda ash and limestone also release carbon dioxide during melting. Moreover, glass production requires mining or producing nonrenewable natural resources such as sand, soda ash, lime and fuel. Transporting them further increases emissions.
Production and fabrication of extra-large glass panels rely on specialized equipment and occur only at a limited number of plants in the world, meaning transportation increases the carbon footprint.
Architectural glass is also difficult to recycle, largely due to the labor involved in separating glass from the building assembly.
Although glass is touted as infinitely recyclable, only 6% of architectural glass is downcycled into glass products that require less purity and precision, and almost none is recycled into architectural glass. The rest ends up in landfills.
The increasing demand for glass that is colorless, extra large and seamless contributes to glass’s sustainability problem.
How can we make glass more sustainable?
There are ways to reduce glass’s environmental footprint.
Researchers and companies are working on new types of glass that could lower its climate impact, such as using materials that lower the amount of heat necessary to make glass. Replacing natural gas, typically used in glassmaking, with less-polluting power sources can also reduce emissions.
Low-e coatings, a thin coat of silver sprayed onto a glass surface, can help reduce the amount of heat that reaches a building’s interior by reflecting both the visible light and heat, but the coating can’t fully eliminate solar heat gain.
People can also alter their standards and accept smaller and less ultraclear panels. Think of the green tint not as impure but natural.
This article is republished from The Conversation under a Creative Commons license. Read the original article.
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Where does your glass come from? (2025, September 10)
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Tech
Is AI ready for the courtroom? New framework tackles the technology’s biggest weaknesses
For over a decade, computer scientist Randy Goebel and his colleagues in Japan have been using a tried-and-true method from his field to advance artificial intelligence in the world of law: a yearly competition.
Drawing on example legal cases taken from the Japanese bar exam, contestants must use an AI system that can retrieve statutes relevant to the cases, and, more crucially, make a decision: did the defendants in the cases break the law, or not?
It’s this yes/no answer that AI struggles with the most, says Goebel—and it raises questions of whether AI systems can be ethically and effectively deployed by lawyers, judges and other legal professionals who face giant dockets and narrow time windows to deliver justice.
The contest has provided the foundation for a new paper in which Goebel and his co-authors outline the types of reasoning AI must use to “think” like lawyers and judges, and describe a framework for imbuing large language models (LLMs) with legal reasoning.
The paper is published in the journal Computer Law & Security Review.
“The mandate is to understand legal reasoning, but the passion and the value to society is to improve judicial decision-making,” Goebel says.
The need for these kinds of tools has been especially critical since the Supreme Court of Canada’s Jordan decision, Goebel says. That decision shortened the length of time prosecutors have to bring a case to trial, and it has resulted in cases as severe as sexual assault and fraud being thrown out of court.
“It’s a very good motivation to say, ‘Let’s enable the judicial system to be faster, more effective and more efficient,'” Goebel says.
Making machines ‘think’ like lawyers
The paper highlights three types of reasoning AI tools must possess to think like legal professionals: case-based, rule-based and abductive reasoning.
Some AI systems, such as LLMs, have proven adept at case-based reasoning, which requires legal experts to examine previous court cases and determine how laws were applied in the past to draw parallels to the current case in question.
Rule-based reasoning, which involves applying written laws to unique legal cases, can also be completed to some extent by AI tools.
But where AI tools struggle the most is with abductive reasoning, a type of logical inference that involves stringing together a plausible series of events that could explain, for example, why a defendant is not guilty of a crime. (Did the man with the knife in his hand stab the victim? Or did a gust of wind blow the knife into his hand?)
“Not surprisingly, abductive reasoning can’t be done by modern large language models, because they don’t reason,” Goebel says. “They’re like your friend who has read every page of Encyclopedia Britannica, who has an opinion on everything but knows nothing about how the logic fits together.”
Combined with their tendency to “hallucinate,” or invent “facts” wholesale, generic LLMs applied to the legal field are at best unreliable and, at worst, potentially career-ending for lawyers.
The important challenge for AI scientists is whether they can develop a reasoning framework that works in conjunction with generic LLMs to focus on accuracy and contextual relevance in legal reasoning, Goebel says.
No one-size-fits-all AI tool
When will we have AI tools that can cut the work of lawyers and judges in half? Perhaps not any time soon.
Goebel says a key takeaway from the competition, and one that is also outlined in the paper, is that using computer programs to aid legal decision-making is relatively new, and there is still a lot of work to be done.
Goebel foresees many separate AI tools employed for different types of legal tasks, rather than a single “godlike” LLM.
Claims made by some in the AI industry that humanity is on the cusp of creating an AI tool that can render “perfect” judicial decisions and legal arguments are absurd, Goebel says.
“Every judge I’ve spoken to has acknowledged there is no such thing as perfect judgment,” he says. “The question is really, ‘How do we determine whether the current technologies provide more value than harm?'”
More information:
Ha Thanh Nguyen et al, LLMs for legal reasoning: A unified framework and future perspectives, Computer Law & Security Review (2025). DOI: 10.1016/j.clsr.2025.106165
Citation:
Is AI ready for the courtroom? New framework tackles the technology’s biggest weaknesses (2025, October 28)
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Tech
Molecular engineering strategy boosts efficiency of inverted perovskite solar cells
Solar cells, devices that can directly convert radiation emitted from the sun into electricity, have become increasingly widespread and are contributing to the reduction of greenhouse gas emissions worldwide. While existing silicon-based solar cells have attained good performances, energy engineers have been exploring alternative designs that could be more efficient and affordable.
Perovskites, a class of materials with a characteristic crystal structure, have proved to be particularly promising for the development of low-cost and energy-efficient solar energy solutions. Recent studies specifically highlighted the potential of inverted perovskite solar cells, devices in which the extraction charge layers are arranged in the reverse order compared to traditional designs.
Inverted perovskite solar cells could be more stable and easier to manufacture on a large-scale than conventional perovskite-based cells. Nonetheless, most inverted cells developed so far were found to exhibit low energy-efficiencies, due to the uncontrolled formation of crystal grains that can produce defects and adversely impact the transport of charge carriers generated by sunlight.
Researchers at Huazhong University of Science and Technology recently devised a new molecular engineering strategy to control the crystallization of perovskite materials in inverted solar cells. This promising approach, outlined in a paper published in Nature Energy, entails mixing special naphthalene-based molecules into perovskites, to ensure that they grow more uniformly.
“Formamidinium and cesium metal halide perovskites enable high efficiency in inverted perovskite solar cells, but uncontrolled crystallization limits their performance,” wrote Qisen Zhou, Guoyu Huang and their colleagues in their paper. “We regulate the nucleation and growth of the perovskite through aromatic interactions between naphthalene ammonium salts and naphthalenesulfonates.”
Essentially, the researchers mixed naphthalene-based molecules into the perovskite solution to control the formation and growth of perovskite crystals. They found that the resulting perovskite films were uniform and had very few defects, which is highly favorable for the development of inverted solar cells.
“The ammonium groups of the naphthalene ammonium salts occupy the formamidinium site, while the sulfonate groups of the naphthalenesulfonates coordinate with lead ions,” explained the authors. “Their naphthalene moieties form tight aromatic stacking adjacent to the [PbI6]4− octahedra. These interactions promote ordered out-of-plane crystallization along the (100) plane, enhancing defect passivation and carrier transport.”
Zhou, Huang and his colleagues used the uniform perovskite films they created to fabricate inverted perovskite solar cells. They then tested the performance, efficiency and stability of these cells under continuous illumination.
“We achieve a power conversion efficiency of 27.02% (certified 26.88%) for inverted solar cells,” wrote the researchers. “Encapsulated devices retain 98.2% of their initial efficiency after 2,000 h of maximum power point tracking under continuous illumination in ambient air. Furthermore, we demonstrate a certified steady-state efficiency of 23.18% for inverted mini-modules with an aperture area of 11.09 cm2 and a certified efficiency of 29.07% for all-perovskite tandem solar cells.”
The initial results gathered by this research team are highly promising, highlighting the promise of their molecular engineering approach for the development of energy-efficient inverted perovskite solar cells. In the future, their strategy could be further refined to achieve additional efficiency gains and used to realize high-quality perovskite films with varying compositions.
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More information:
Qisen Zhou et al, Aromatic interaction-driven out-of-plane orientation for inverted perovskite solar cells with improved efficiency, Nature Energy (2025). DOI: 10.1038/s41560-025-01882-x
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Molecular engineering strategy boosts efficiency of inverted perovskite solar cells (2025, October 28)
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Tech
The Republican Plan to Reform the Census Could Put Everyone’s Privacy at Risk
President Donald Trump and the Republican Party have spent the better part of the president’s second term radically reshaping the federal government. But in recent weeks, the GOP has set its sights on taking another run at an old target: the US census.
Since the first Trump administration, the right has sought to add a question to the census that captures a respondent’s immigration status and to exclude noncitizens from the tallies that determine how seats in Congress are distributed. In 2019, the Supreme Court struck down an attempt by the first Trump administration to add a citizenship question to the census.
But now, a little-known algorithmic process called “differential privacy,” created to keep census data from being used to identify individual respondents, has become the right’s latest focus. WIRED spoke to six experts about the GOP’s ongoing effort to falsely allege that a system created to protect people’s privacy has made the data from the 2020 census inaccurate.
If successful, the campaign to get rid of differential privacy could not only radically change the kind of data made available, but could put the data of every person living in the US at risk. The campaign could also discourage immigrants from participating in the census entirely.
The Census Bureau regularly publishes anonymized data so that policymakers and researchers can use it. That data is also sensitive: Conducted every 10 years, the census counts every person living in the United States, citizen and noncitizen alike. The data includes detailed information like the race, sex, and age, as well the languages they speak, their home address, economic status, and the number of people living in a house. This data is used for allocating the federal funds that support public services like schools and hospitals, as well as for how a state’s population is divided up and represented in Congress. The more people in a state, the more Congressional representation—and more votes in the Electoral College.
As computers got increasingly sophisticated and data more abundant and accessible, census employees and researchers realized the data published by the Census Bureau could be reverse engineered to identify individual people. According to Title XIII of the US Code, it is illegal for census workers to publish any data that would identify individual people, their homes, or businesses. A a government employee revealing this kind of information could be punished with thousands of dollars in fines or even a possible prison sentence.
For individuals, this could mean, for instance, someone could use census data without differential privacy to identify transgender youth, according to research from the University of Washington.
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